Production of higher molecular weight hydrocarbons from methane

Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – To produce unsaturate

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585500, 585641, 585943, C07C 100

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active

047147962

ABSTRACT:
A process for oxidative pyrolysis of halogenated methanes in the presence of oxygen-containing gas under non-flame conditions is provided whereby the formation of solid carbonaceous materials is significantly reduced, while high yields of desired higher molecular weight hydrocarbons such as acetylene and ethylene are maintained.

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Back, M. H. and Back, R. A., "Thermal Decomposition and Reactions of Methane", Pyrolysis: Theory and Industrial Practice, Albright, L. F., Crynes, B. L. and Corcoran, W. H., Eds., Academic Press, New York, N.Y., p. 1 (1983).
Weissman, M., and Benson, S., "Pyrolysis of Methyl Chloride, a Pathway in the Chlorine-Catalyzed Polymerization of Methane", Int. J. Chem. Kinetics, vol. 16, p. 307 (1984).
Senkan, S. M., Robinson, J. M., and Gupta, A. K., "Sooting Limits of Chlorinated Hydrocarbon-Methane-Air Premixed Flames", Combust. Flame, vol. 49, p. 305 (1983).
Frenklach, M., Hsu, J. P., Miller, D. L., and Matula, R. A., "Shock-Tube Pyrolysis of Chlorinated Hydrocarbons: Formation of Soot", Combust. Flame, vol. 64, p. 141 (1986).

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