Production of high (Z,Z) content 1,5,9-tetradecatriene

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – Product having more than two double bonds

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585646, C07C 202, C07C 1121

Patent

active

046544615

ABSTRACT:
Method for the production of high cis content 1,5,9-tetradecatriene is provided which comprises disproportionating 1,5-cyclooctadiene and 1-hexene in the presence of a catalyst consisting essentially of molybdenum oxide on a high purity, high surface area, high pore volume silica support. The resulting high cis content 1,5,9-tetradecatriene is a useful precursor for the preparation of gossyplure, a known insect sex attractant.

REFERENCES:
patent: 3365513 (1968-01-01), Heckelsberg
patent: 3586731 (1971-06-01), Heckelsberg
patent: 3637893 (1972-01-01), Singleton
patent: 3658927 (1972-04-01), Crain et al.
patent: 3715410 (1973-02-01), Ray et al.
patent: 3739037 (1973-06-01), Cywinski
patent: 4331814 (1982-05-01), Chabardes et al.

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