Production of high purity butadiene

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585366, 585367, 585832, C07C 500, C07C 5333

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active

042257387

ABSTRACT:
This invention provides a three-step process for converting n-butene into high purity 1,3-butadiene, via a vinylcyclohexene intermediate.
In the first step of the process, n-butene and molecular oxygen are contacted with a Group VIII metal oxide catalyst. If nitrobenzene is employed as the oxidizing agent in place of molecular oxygen then aniline is produced as a secondary product of the process.

REFERENCES:
patent: 2355392 (1944-08-01), Oberfell
patent: 2423179 (1947-07-01), Doumani et al.
patent: 2433465 (1947-12-01), Leum et al.
patent: 4117025 (1978-09-01), Liebert et al.

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