Production of high molecular weight .alpha.,.beta.-unsaturated a

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2603409R, C07D31904

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active

040585360

ABSTRACT:
A process for the production of high molecular weight .alpha.,.beta.-unsaturated aldehydes by alkylation of the .gamma.-carbon atom of a lower molecular weight .alpha.,.beta.-unsaturated aldehyde with a substituted allyl alcohol which has a chain branching in the 3-position carbon atom or a phenyl radical in the 3-position or of a corresponding allyl alcohol carboxylic ester at elevated temperature in the liquid phase.
The products are valuable intermediates for the production of natural substances and odorants.

REFERENCES:
patent: 3654309 (1972-04-01), Thomas
patent: 3862235 (1975-01-01), Himmele et al.
patent: 3932462 (1976-01-01), Goetz et al.
patent: 3954804 (1976-05-01), Fischer et al.
patent: 3965193 (1976-06-01), Goetz et al.
patent: 4021411 (1977-05-01), Goetz et al.

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