Chemistry of inorganic compounds – Sulfur or compound thereof – Binary compound
Patent
1977-06-16
1979-02-27
Vertiz, O. R.
Chemistry of inorganic compounds
Sulfur or compound thereof
Binary compound
423242, C01B 1700, C01B 1716
Patent
active
041419618
ABSTRACT:
This invention is a process for producing gaseous hydrogen sulfide in concentrated form from sulfur dioxide obtained from a dilute gas source by (1) reacting the SO.sub.2 with Na.sub.2 CO.sub.3 to form Na.sub.2 SO.sub.3, (2) reducing the Na.sub.2 SO.sub.3 to Na.sub.2 S, (3) reacting the Na.sub.2 S with NaHCO.sub.3 to form H.sub.2 S and Na.sub.2 CO.sub.3, (4) recycling part of the Na.sub.2 CO.sub.3 to the SO.sub.2 reaction step, (5) reacting the remainder of the Na.sub.2 CO.sub.3 with CO.sub.2 and H.sub.2 O to form NaHCO.sub.3 and (6) recycling the NaHCO.sub.3 to the H.sub.2 S formation reaction.
REFERENCES:
patent: 3508863 (1970-04-01), Kiminki et al.
patent: 3832444 (1974-08-01), Doyle
patent: 3932586 (1976-01-01), Guerriere
patent: 3932587 (1976-01-01), Grantham et al.
patent: 3987147 (1976-10-01), Guerriere
patent: 4003985 (1977-01-01), Hoffman et al.
Proceeding: Symposium on Flue Gas Desulfurization, New Orleans, Mar. 1976, vol. II, EPA-600/2-76-136b, May 76, pp. 787-797.
DTPM Corporation
Straub Gary P.
Vertiz O. R.
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