Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking
Patent
1989-09-11
1990-12-25
McFarlane, Anthony
Mineral oils: processes and products
Chemical conversion of hydrocarbons
Cracking
585651, 585653, C10G 1105
Patent
active
049800531
ABSTRACT:
Various fractions of petroleum, including residual oils and crude oils, are catalytically converted to produce gaseous olefins, especially propylene and butylene, in fluidized or moving bed or transfer line reactors with solid, acidic catalysts in the presence of steam at a temperature of 500.degree. to 650.degree. C. and a pressure of 1.5.times.10.sup.5 Pa to 3.times.10.sup.5 Pa, with a weight space velocity of 0.2 to 20 hr.sup.-1 and catalyst-to-oil ratio of 2 to 12. Spent catalyst is continuously removed from the reactor to a regenerator where the coke is burned off and the hot catalyst is returned to the reactor. In a comparison with conventional catalytic cracking and tubular furnance pyrolysis processes, it is found that the process of the present invention produces more propylene and butylene. The total yield of the process of the present invention is about 40 percent by weight of the feedstock.
REFERENCES:
patent: 3053752 (1962-09-01), Swanson
patent: 3290405 (1966-12-01), Rosenberg
patent: 3541179 (1970-11-01), Okagami et al.
patent: 3647682 (1972-03-01), Rabo et al.
patent: 4551231 (1985-11-01), Kovach et al.
patent: 4717466 (1988-01-01), Herbst et al.
Ge Xingpin
Li Zaiting
Liu Shunhua
McFarlane Anthony
Research Institute of Petroleum Processing Sinopec
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