Production of fluid fertilizer from phosphorus furnace waste str

Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing

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423322, 423323, C01B 2516

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active

045143668

ABSTRACT:
Processes and compositions of matter are disclosed for the production of liquid fertilizers wherein wastewater from a phosphorus smelting furnace is incorporated in liquid fertilizer processes. The wastewater replaces water evaporated and the wastewater dissolves fertilizer salts. A serious water pollution problem is avoided when wastewater is incorporated in liquid fertilizers. The invention discloses a process for making orthophosphate suspension fertilizer wherein impure phosphoric acid is neutralized in the condensing system, water from the condensing system is bled off, and a suspending clay is added to produce orthophosphate suspension fertilizer. In this process, phosphorus sludge made at phosphorus furnaces is used to produce suspension fertilizer, and wastewater from phosphate smelting furnaces is recovered. New compositions of matter are disclosed. A process is disclosed for making phosphoric acid with low impurities content wherein phosphorus sludge is burned to make impure orthophosphoric acid and the impure acid is recycled to an agglomerating step in a process for making elemental phosphorus.

REFERENCES:
patent: 2020976 (1935-11-01), Udy
patent: 2267077 (1941-12-01), Burke
Production of Elemental Phosphorus by the Electric Furnace Method, _TVA, Chemical Engineering Report No. 3, 1952, reprinted 1967.
"Development of a Wastewater Management System for an Elemental Phosphorus Production Plant", Koon et al., 35th Ind. Waste Conference, 1980.
Barber, "Waste Efficient Treatment and Reuse Chemical Engineering Progress, Jun. 1969.
Agglomeration of Phosphate Fines for Furnace Use, Chemical Engineering Report, No. 4, TVA, 1950.

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