Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Molecular oxygen or ozone component
Patent
1988-06-10
1989-08-22
Cooper, Jack
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Molecular oxygen or ozone component
4232453, 423262, 423351, 423415A, 423437, 423651, C01B 2104, C01B 2300
Patent
active
048594342
ABSTRACT:
The present invention is directed to a process for producing endothermic gases from methanol and inert gas streams containing minor amounts of oxygen, wherein the oxygen is reacted with stoichiometric excess quantities of methanol over a catalyst as ambient feed temperature conditions without a requirement for external heating of the reaction to produce an endothermic gas containing very low levels of oxygen and methanol and significant quantities of hydrogen, carbon monoxide, water and carbon dioxide.
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patent: 4304761 (1981-12-01), Yu Yao
patent: 4673556 (1987-06-01), McCabe et al.
"Gold and Platinum Catalyzed Oxidation of Methanol", by Collin N. Hodges and Leonard C. Roselaar, in Journal of Applied Chemical Bio-Technology, vol. 25, pp. 609-614, (1975).
"Catalytic Oxidation of Methanol Over Platinum", by J. G. Firth in Trans Faraday Society, vol. 67, p. 212, (1971).
"A Model for Carbon Transfer in Gas-Phase Carburization of Steel", in Journal of Heat Treating, vol. 1, No. 4, p. 27, by Kaspersma and Shay.
"Two-Step Accelerated Carburizing Shortens Cycle, Saves Energy", in Heat Treating, Jul. 1981, p. 36 by Peartree.
Roberts George W.
Sircar Shivaji
Stepanoff Paul
Air Products and Chemicals Inc.
Chase Geoffrey L.
Cooper Jack
Marsh William F.
Simmons James C.
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