Production of durene and gasoline from synthesis gas

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585469, 585640, 585733, 585812, 585814, C07C 104

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045242283

ABSTRACT:
Synthesis gas is catalytically converted to a feedstock comprising durene and gasoline. Durene is recovered from the feedstock by cooling it to a point where crystallization occurs and separating the crystallized durene. The durene subsequently is washed with a wash fluid. The wash fluid which can be methanol, is returned to a process wherein it is converted to gasoline and durene. The separated mother liquor is added to the gasoline fraction.

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Nakamura et al, J. Industrial Chemistry, vol. 71, No. 11, pp. 1851-1855 (1968).
Scheeline, Trimellitic and Pyromellitic Anhydrides, Stanford Research Institute, California (1970).

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