Production of cyclic hydrocarbons from normal octenes

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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585365, 585414, 585418, 585419, C07C 8511, C07C 1542, C07C 1246, C07C 531

Patent

active

042462029

ABSTRACT:
This invention provides a process for the production of cyclic hydrocarbons from light olefinic hydrocarbons which involves contacting n-octene feed with a Group VIII metal oxide catalyst in the presence of molecular oxygen at temperatures of 130.degree.-500.degree. C. and a pressure of 1-200 psi to yield vinylcyclohexene and ethylbenzene.
The invention further provides a two step vapor phase process embodiment for converting n-octene feed to styrene via a vinylcyclohexene/ethylbenzene intermediate mixture. When nitrobenzene is employed as the oxidizing agent in place of molecular oxygen, aniline is obtained as an additional product.

REFERENCES:
patent: 3308193 (1967-03-01), Bajars
patent: 3686341 (1972-08-01), Eberly

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