Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing
Patent
1983-06-28
1984-02-14
Carter, Herbert T.
Chemistry of inorganic compounds
Oxygen or compound thereof
Metal containing
423 53, 423520, 423551, C01G 37033
Patent
active
044316259
ABSTRACT:
Chromium trioxide is made by reacting sodium dichromate with sulphuric acid in an aqueous reaction mixture, evaporating the resultant liquor to cause crystallization of most of the chromium trioxide and to cause the concentration of sodium sulphates to be close to but below that at which sulphate crystals start to form, and separating the chromium trioxide crystals from the evaporated liquor. The liquor may then be cooled so as to cause crystallization of sodium sulphates, generally as sodium bisulphate, and the resultant liquor, after separation of the crystals, may be recycled to the reaction mixture containing dichromate and sulphuric acid.
REFERENCES:
patent: 2034256 (1936-03-01), Vetter
patent: 2632688 (1953-03-01), Perrin
patent: 3002815 (1961-10-01), Heinze
Marshall Michael A.
Swales Danvers A.
British Chrome & Chemicals Limited
Carter Herbert T.
Rosen Lawrence
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