Production of chlorine dioxide in an electrolytic cell

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204 95, 204129, 204 98, C25B 126

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active

048530964

ABSTRACT:
Chlorine dioxide is produced electrolytically in the cathode compartment of an electrolytic cell using a three-dimensional high surface-area cathode. The cathode compartment is separated from an anode compartment by a cation-exchange membrane. Sodium chlorate is reacted with hydrogen ions and chloride ions in the cathode compartment and chlorine dioxide is vented from the cathode compartments. Chlorine co-produced with the chlorine dioxide is reduced at the cathode to provide chloride ions for the reaction while electrolytically-produced hydrogen ions are transferred across the membrane from the anode compartment to the cathode compartment to provide hydrogen ions for the reaction.

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patent: 3904496 (1975-09-01), Harke et al.
patent: 3920801 (1975-11-01), Grotheer
patent: 4294815 (1981-10-01), Lohrberg et al.
patent: 4308117 (1981-12-01), Sweeney
patent: 4324635 (1982-04-01), Sweeney
patent: 4426263 (1984-01-01), Hardee et al.
patent: 4456510 (1984-06-01), Murakami et al.
patent: 4767510 (1988-08-01), Lipsztajn

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