Production of biodiesel and glycerin from high free fatty...

Fuel and related compositions – Liquid fuels – Plant or animal extract mixtures or extracts of...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C554S167000

Reexamination Certificate

active

07871448

ABSTRACT:
A system and method for the conversion of free fatty acids to glycerides and the subsequent conversion of glycerides to glycerin and biodiesel includes the transesterification of a glyceride stream with an alcohol. The fatty acid alkyl esters are separated from the glycerin to produce a first liquid phase containing a fatty acid alkyl ester rich (concentrated) stream and a second liquid phase containing a glycerin rich (concentrated) stream. The fatty acid alkyl ester rich stream is then subjected to distillation, preferably reactive distillation, wherein the stream undergoes both physical separation and chemical reaction. The fatty acid alkyl ester rich stream is then purified to produce a purified biodiesel product and a glyceride rich residue stream. Biodiesel may be further recovered from the glyceride rich residue stream, by further separation of and/or processing of glycerides/free fatty acids contained therein. The glycerin rich second liquid phase stream may further be purified to produce a purified glycerin product and a (second) wet alcohol stream. Neutralization of the alkaline stream, formed during the alkali-catalyzed transesterification process, may proceed by the addition of a mineral or an organic acid.

REFERENCES:
patent: 1659790 (1928-02-01), Starrels
patent: 2290609 (1942-07-01), Goss et al.
patent: 2383580 (1945-08-01), Arrowsmith et al.
patent: 2383581 (1945-08-01), Arrowsmith et al.
patent: 2383601 (1945-08-01), Kelm
patent: 2385599 (1945-08-01), Glossop
patent: 2383596 (1948-08-01), Dreger
patent: 2494366 (1950-01-01), Sprules et al.
patent: 2543421 (1951-02-01), Price et al.
patent: 2588435 (1952-03-01), van Loon et al.
patent: 2808421 (1957-10-01), Brokaw
patent: 2875221 (1959-02-01), Birnbaum
patent: 3102129 (1963-08-01), Birnbaum et al.
patent: 3459736 (1969-08-01), Dallbor
patent: 4164506 (1979-08-01), Kawahara et al.
patent: 4267393 (1981-05-01), Torck et al.
patent: 4303590 (1981-12-01), Tanaka et al.
patent: 4364743 (1982-12-01), Erner
patent: 4371470 (1983-02-01), Matsukura et al.
patent: 4668439 (1987-05-01), Billenstein et al.
patent: 4695411 (1987-09-01), Stern et al.
patent: 4698186 (1987-10-01), Jeromin et al.
patent: 4839287 (1989-06-01), Holmberg et al.
patent: 4956286 (1990-09-01), Macrae
patent: 5354878 (1994-10-01), Connemann et al.
patent: 5399731 (1995-03-01), Wimmer
patent: 5424467 (1995-06-01), Bam et al.
patent: 5434279 (1995-07-01), Wimmer
patent: 5514820 (1996-05-01), Assmann et al.
patent: 5525126 (1996-06-01), Basu et al.
patent: 5578090 (1996-11-01), Bradin
patent: 5646311 (1997-07-01), Hunt et al.
patent: 5697986 (1997-12-01), Haas
patent: 5713965 (1998-02-01), Foglia et al.
patent: 5847239 (1998-12-01), Davey et al.
patent: 5908946 (1999-06-01), Stern et al.
patent: 6013817 (2000-01-01), Stern et al.
patent: 6015440 (2000-01-01), Noureddini
patent: 6075158 (2000-06-01), Hill
patent: 6090959 (2000-07-01), Hirano et al.
patent: 6127560 (2000-10-01), Stidham et al.
patent: 6127561 (2000-10-01), Jeromin et al.
patent: 6174501 (2001-01-01), Noureddini
patent: 6211390 (2001-04-01), Peter et al.
patent: 6262285 (2001-07-01), McDonald
patent: 6288251 (2001-09-01), Tsuto et al.
patent: 6398707 (2002-06-01), Wu et al.
patent: 6399800 (2002-06-01), Haas et al.
patent: 6440057 (2002-08-01), Ergun et al.
patent: 6489496 (2002-12-01), Barnhorst et al.
patent: 6500974 (2002-12-01), Thengumpillil et al.
patent: 6642399 (2003-11-01), Boocock
patent: 6822105 (2004-11-01), Luxen et al.
patent: 6965043 (2005-11-01), Kenneally et al.
patent: 7087771 (2006-08-01), Luxen et al.
patent: 2002/0111504 (2002-08-01), Peter et al.
patent: 2002/0156305 (2002-10-01), Turck
patent: 2003/0083514 (2003-05-01), Boocock
patent: 2003/0149289 (2003-08-01), Suppes
patent: 2003/0229238 (2003-12-01), Fleisher
patent: 2006/0074256 (2006-04-01), Alasti
patent: 2007/0277429 (2007-12-01), Jackam
patent: 2007/0277430 (2007-12-01), Jackam
patent: 197 24 018 (1998-12-01), None
patent: 0591019 (1997-08-01), None
patent: 0708813 (2001-02-01), None
patent: 587532 (1947-04-01), None
patent: 612667 (1948-11-01), None
patent: 2 350 618 (2000-12-01), None
patent: WO 95/02661 (1995-01-01), None
patent: 9924387 (1999-05-01), None
patent: WO02/28811 (2002-04-01), None
patent: WO02/38529 (2002-05-01), None
Muniyappa et al; Improved Conversion of Plant Oils and Animal Fats Into Biodiesel and Co-Product; Jun. 1996; Elsevier Science Limited, 0960-8524/96 (Abstract).
Tyson, Biodiesel Research Progress 1992-1997; pp. 1-301; National Renewable Energy Laboratory; Boulder Co.; Feb. 1997.
Gerpen et al; Biodiesel Production Technology Aug. 2002-Jan. 2004; pp. 1-106; Jul. 2004; National Renewable Energy Laboratory; Boulder Co.
Biodiesel in North America: Implementation Issues; IEA Bioenergy Task 39; pp. 1-165; Feb. 28, 2004; S&T Consultants Inc., Canada.
Hildebrandt; Kinetic Investigation of the Base-Catalyzed Glycerolysis of Fatty Acid Methyl Esters; pp. 1-183; Nov. 5, 2004.
Lago, R.C.A., R.R. Szpiz, F.H. Jablonka, D.A. Pereira and L. Hartman; “Extraction and Transesterification of Vegetable Oils with Ethanol”; pp. 147-154; vol. 40, No. 3; Oleagineux; Paris, France, 1985.
Ma, Fangrui and Milford A. Hannah; “Biodiesel Production: a review”; pp. 1-15; vol. 70, No. 1; Bioresource Technology Elsevier, GB, 1999.
Kiss, A.A., A.C. Dimian, F. Omota, “Sustainable biodiesel production by integrated process design”, 2005, van't Hoff Institute for Molecular Sciences, University of Amsterdam, The Netherlands, 2005.
Noureddini et al., Glycerolysis of Fats and Methyl Esters, JAOCS, 1997, pp. 419-425, vol. 74, No. 4; Lincoln, NE.
Tyson, Brown Grease Feedstocks for Biodiesel, WWW domain nrel.gov, 2002, pp. 1-33; National Renewable Energy Technology, CO.
Tyson, Biodiesel Technology and Feedstocks, WWW domain nrel.gov, 2003, pp. 1-37; National Renewable Energy Technology, CO.
Clements, Pretreatment of High Free Fatty Acid Feedstocks, Biodiesel Production Technology Workshop III, Mar. 26, 2003, pp. 78c-78i; Iowa State University, Lincoln, NE.
Yuan, W. et al. Vapor pressure and normal boiling point predictions for pure methyl esters and biodiesel fuels. Fuel, 84, 2005, 943-950.
Gouw, T.H. et al. Physical Properties of Fatty Acid Methyl Esters. I. Density and Molar Volume. The Journal of the American Oil Chemists' Society, 41, 1964, 142-145.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Production of biodiesel and glycerin from high free fatty... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Production of biodiesel and glycerin from high free fatty..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Production of biodiesel and glycerin from high free fatty... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2673284

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.