Production of binders for coating compositions

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 86, 526209, 526225, 526229, 526303, 526317, 526342, 526347, 526336, C08F 226, C08F23604, C08F21208

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039766268

ABSTRACT:
Binders for coating compositions are produced by an elevated temperature, aqueous phase polymerization, in the presence of an anionic emulsifier, polyethylene oxide and peroxydisulfate, of a monomer mixture consisting by weight of 10-85% vinyl aromatic component, which may be partially replaced by 0-20% of acrylonitrile, 15-90% by weight of diolefin component and up to 6% each of .beta.-unsaturated carboxylic acid or an amide thereof or a mixture thereof, characterized by employing a starting reaction mixture containing 0.05-0.5% of an anionic sulfonate or sulfate emulsifier; 0.5-5% of a polyethylene oxide having an average molecular weight of between 300 and 4,000; and 0.5-2% of a water-soluble peroxydisulfate; and, after a monomer conversion of between 15 and 35% by weight, adding to the reaction mixture another 0.2-1.5% of an anionic sulfonate or sulfate emulsifier.

REFERENCES:
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patent: 2836584 (1958-05-01), Wheelock et al.
patent: 3142654 (1964-07-01), Peterson et al.
patent: 3188304 (1965-06-01), Goshorn et al.
patent: 3471591 (1969-10-01), Lindsey
patent: 3547857 (1970-12-01), Murray
patent: 3843584 (1974-10-01), Turck

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