Production of binary rare earth/sulfur or transition metal/sulfu

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Rare earth metal

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423263, 4235611, 423562, 423563, 423565, 423567, C01F 1700, C01G 112

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active

052798011

ABSTRACT:
Binary rare earth/sulfur or transition metal/sulfur compounds, e.g., the higher sulfides or sesquisulfides of the rare earths, are prepared by confinedly reacting either a rare earth compound, e.g., an oxide, carbonate or hydroxide, or a transition metal oxide, with a carbon compound of sulfur in gaseous state, e.g., CS.sub.2, within a sealed enclosure.

REFERENCES:
patent: 3748095 (1973-07-01), Henderson et al.
patent: 4863882 (1989-09-01), Matsuda et al.
Nippon Kagaku Kaishi, (12), 2438-40/1972 Au Toide, et al.
Journal of Physics E. Scientific Instruments, vol. 3, No. 4, (Apr. 1970), Ishing, Bristol GB p. 317 S. Marich: "The Preparation of High Purity, Metal-Sulfur Alloys".
Gmelin: "Handbook of Inorganic Chemistry" 1983, Springer Verlag, berlin, 8th Ed. part C7, System 39, p. 70, line 5, p. 72, line 1.
Chemical Abstracts, vol. 91, No. 14, Oct. 1979, Columbus, Ohio T. Matsuoka et al: "Metal sulfide with high melting point" p. 101, ref. No. 109611 E.

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