Production of aromatic polyketones

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528128, 528173, 528176, 528179, 528190, 528191, 528193, 528206, 528207, 528220, 528223, 528271, 528360, 528364, C08G 6700

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active

043967558

ABSTRACT:
Production of an aromatic polyketone by reacting in the presence of a quinquevalent phosphorous halide (preferably PCl.sub.5) and a fluoroalkane sulphonic acid (preferably CF.sub.3 SO.sub.2 OH) the reactants selected from: (a) a mixture of (i) at least one aromatic dicarboxylic acid HO.sub.2 C--Ar--CO.sub.2 H where --Ar'-- is a divalent aromatic radical and CO.sub.2 H is an aromatically bound carboxylic acid group, which dicarboxylic acid is polymerizable with the at least one aromatic compound of (ii), and (ii) at least one aromatic compound H--Ar'--H where --Ar'-- is a divalent aromatic radical and H is an aromatically bound hydrogen atom, which compound is polymerizable with the at least one dicarboxylic acid of (i); (b) at least one aromatic monocarboxylic acid H--Ar"--CO.sub.2 H where --Ar"-- is a divalent aromatic radical and H and CO.sub.2 H are as defined in (a), which monocarboxylic acid is self-polymerizable; and (c) a combination of (a) and (b).

REFERENCES:
patent: 3065205 (1962-11-01), Bonner, Jr.
patent: 3324199 (1967-06-01), Tocker
patent: 4247682 (1981-01-01), Dahl
"Polyarylsulfones, Synthesis and Properties," Journal of Polymer Science, Part A-1, vol. 8, 2035-2047 (1970), H. A. Vogel.

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