Production of anhydrous aluminum chloride from clay using cataly

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group iiia metal or beryllium

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423136, 423495, 423341, 75113, C01F 756, C01F 758

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040962342

ABSTRACT:
Aluminum chloride is produced from clay containing aluminum oxide and silicon oxide by chlorinating the clay through contact with a mixture consisting essentially of a chlorinating agent, a reducing agent, an alkali metal compound catalyst, and silicon chloride; and thereafter separating the reaction products from the chlorination step; and recycling back to the chlorination step substantially all the silicon chloride separated from the reaction products to thereby promote the chlorination of the aluminum oxide in the clay while suppressing chlorination of the silicon oxide.

REFERENCES:
patent: 1865008 (1932-06-01), Holm
patent: 1866731 (1932-07-01), Staib
patent: 1875105 (1932-08-01), Muggleton
Seferovich, "Journal of Chemical Industry (Moscow)", vol. 10, 1934, pp. 62-64.
Hilli et al., "Angew. Chem.", vol. 72, 1960, pp. 850-855.

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