Production of ammonia from purified ammonia synthesis gas

Chemistry of inorganic compounds – Nitrogen or compound thereof – Ammonia or ammonium hydroxide

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423648R, 423650, C01C 104

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active

044696655

ABSTRACT:
A moist hydrogen stream is dried by cooling to below the dewpoint of water and separating water, drying further over a regenerable solid absorbent, separating a part stream of dried gas and using it to regenerate water-loaded absorbent, and recycling the resulting moist regeneration gas stream into the moist hydrogen stream upstream of the water separation step. If the starting moist hydrogen stream is produced by shift, CO.sub.2 -removal and methanation the recycled gas is preferably introduced between CO.sub.2 removal and methanation. If it is produced from unreacted methanol synthesis gas the recycled gas is preferably introduced upstream of methanol synthesis.

REFERENCES:
patent: 2629460 (1953-02-01), Maki
patent: 3150942 (1964-09-01), Vasan
patent: 3350170 (1967-10-01), Finneran et al.
patent: 3388968 (1968-06-01), Spielman et al.
patent: 3598527 (1971-08-01), Quartulli et al.
patent: 4242317 (1980-12-01), Pinto
Kirk-Othmer Encyclopedia of Chemical Technology, 3rd Ed., vol. 2, 1978, pp. 494-500.
Kirk-Othmer Encyclopedia of Chemical Technology, 3rd Ed., vol. 8, 1979, pp. 125-127.

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