Production of .alpha., .omega.-dialdehydes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260 784R, 260530R, 260585C, 260635A, 260637R, 423417, C07C 4712

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active

039339203

ABSTRACT:
An improved process for the production of .alpha.,.omega.-dialdehydes by reaction of linear .alpha.,.omega.-diolefins having isolated double bonds with carbon monoxide and hydrogen at elevated temperature and at superatmospheric pressure in the presence of a cobalt carbonyl complex in which the improvement consists in supplying the cobalt to the reaction as cobalt carbonyl hydride dissolved in the .alpha.,.omega.-diolefin to be used or in an inert organic solvent and carrying out the reaction at a temperature of from 70.degree. to 130.degree.C.

REFERENCES:
patent: 2738370 (1956-03-01), Staib et al.
patent: 2748167 (1956-05-01), Hagemeyer et al.
patent: 2985504 (1961-05-01), Orchin

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