Production of alkali metallated olefin polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253317, 525366, C08F 842

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active

053649117

ABSTRACT:
Novel metallated polyolefins are produced by contacting a polyolefin having a vinylidene group in the terminal portion with organoalkali metal compound in the presence of alkali metal t-alkoxide or tertiary amine. The metallated polyolefin is used to initiate the polymerization of polymerizable monomers to produce block copolymers of at least two blocks, at least one of which is saturated polyolefin.

REFERENCES:
patent: 3632678 (1972-01-01), Ehrig et al.
patent: 4078019 (1978-03-01), Langer, Jr.
patent: 4480075 (1984-10-01), Willis
patent: 4761456 (1988-08-01), Lund et al.
Kogyo Kagaku Zasshi, 74(3), 481-4, 1971.

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