Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Reexamination Certificate
2008-05-13
2008-05-13
Eyler, Yvonne (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
C549S249000
Reexamination Certificate
active
07371893
ABSTRACT:
A description is given of a process for preparing aldehydes, carboxylic acids and/or carboxylic anhydrides, in particular phthalic anhydride, in which a gaseous stream comprising an aromatic hydrocarbon and molecular oxygen is passed at elevated temperature over a bed of a first catalyst and a bed which is made up of a second catalyst having a higher activity than the first catalyst and is located downstream of the first catalyst in the flow direction of the gaseous stream, wherein the catalytically active composition of the first catalyst comprises at least vanadium oxide, titanium dioxide and antimony oxide and the ratio of vanadium, calculated as V2O5, to antimony, calculated as Sb2O3, in the first catalyst is from 3.5:1 to 5:1. The source of antimony oxide used for the first catalyst is preferably particulate antimony trioxide having a mean particle size of from 0.5 to 5 μm. The process allows the desired oxidation products to be obtained in high yield over longer periods of time.
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Neto Samuel
Rosowski Frank
Storck Sebastian
Zühlke Jürgen
BASF - Aktiengesellschaft
Connolly Bove & Lodge & Hutz LLP
Eyler Yvonne
Lao M Louisa
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