Production of alcohols and/or aldehydes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260638HF, C07C 4508

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active

039593851

ABSTRACT:
An improved process for the production of aldehydes and alcohols by the oxo process comprising the reaction of olefinically unsaturated compounds with carbon monoxide and hydrogen at elevated temperatures and elevated pressures in the presence of carbonyl complexes of metals in Group VIII of the Periodic Table modified by trisubstituted organic phosphines and in the presence of alkali or alkaline earth metal salts of carboxylic acids, the improvement comprising the use of modifying agents which consist of trisubstituted organic phosphines containing one or more carboxylic acid groups, at least one of which is present in the form of its alkali metal or alkaline earth metal salt.

REFERENCES:
patent: 3239569 (1966-03-01), Slaugh et al.
patent: 3274263 (1966-09-01), Greene et al.
patent: 3400163 (1968-09-01), Mason et al.
patent: 3646079 (1972-02-01), Lawrenson
patent: 3681465 (1972-08-01), Falbe et al.

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