Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By plural serial diverse separations
Patent
1980-12-23
1983-01-04
Waltz, Thomas A.
Chemistry of hydrocarbon compounds
Purification, separation, or recovery
By plural serial diverse separations
585534, 585538, 585539, 585540, 585834, C07C 710
Patent
active
043673635
ABSTRACT:
The process relates to the recovering of essentially pure acetylene from the gaseous out-put stream from a coal to acetylene conversion process. A plasma arc generator or other high energy type reactor can be used for the conversion to coal. The gaseous out-put stream is initially treated in an acid gas removal stage by absorbing HCN and H.sub.2 S in an organic solvent such as N-methyl pyrrolidone and scrubbing with a caustic agent such as NaOH to remove CO.sub.2. In a second stage, the gaseous out-put stream is scrubbed with the organic solvent to provide a sweet gas treatment and remove essentially pure acetylene as a product. In a third stage, the second stage gases are first hydrogenated, then desulferized and then methanated. The out-put from the third stage is recycled to the coal to acetylene conversion process. In a fourth stage, the organic solvent from said second stage is refined and recycled to the first stage and/or second stage.
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Carluccio Frank
Casciano Robert
Desai Ashok
FitzPatrick Kevin
Katz Michael
GAF Corporation
Magee Jr. James
Mohr J. Gary
Waltz Thomas A.
Ward Joshua J.
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