Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction
Patent
1981-10-29
1982-12-28
Mars, Howard T.
Chemistry: fischer-tropsch processes; or purification or recover
Liquid phase fischer-tropsch reaction
252431N, 252431P, 518715, C07C 2706
Patent
active
043662595
ABSTRACT:
This invention concerns a process of making acetic acid and propionic acid and their esters which comprises contacting a mixture of CO and H.sub.2 with a catalyst system comprising a ruthenium-containing compound and a cobalt halide dispersed in a low melting quaternary phosphonium or ammonium base or salt at a temperature of at least about 150.degree. C. and at a pressure of about 500 psig or greater.
REFERENCES:
patent: 2636046 (1953-04-01), Gresham
patent: 4088671 (1978-05-01), Kobylinski
patent: 4265828 (1981-05-01), Knifton
patent: 4315994 (1982-02-01), Knifton
Knifton John F.
Lin Jiang-Jen
Hunter Walter D.
Mars Howard T.
Park Jack H.
Texaco Inc.
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