Production of 5-nitrotetrazole salts

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 314, C07F 110, C07F 108

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040948790

ABSTRACT:
Silver and mercury 5-nitrotetrazole salts are prepared by forming an acid solution of a complex of cupric 5-nitrotetrazole with an aliphatic chelating amine and adding to the acid solution a solution of a soluble silver or mercury salt. The silver or mercury 5-nitrotetrazole salt is precipitated and filtered off. The cupric 5-nitrotetrazole amine complex may first be decomposed by reacting with a mixture of nitric acid and a nitrite and the silver or mercury salt solution then added to precipitate the corresponding 5-nitrotetrazole salt. The silver and mercury nitrotetrazole salts are useful as explosives.

REFERENCES:
patent: 2066954 (1937-01-01), von Herz
Taylor et al, Symp. Chem. Probl. Connected Stab. Explosive [Proc.]3rd 1973 (Pub. 1974) 43-46.

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