Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1980-10-09
1982-03-09
Garner, Vivian
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
260546, 260549, 562517, C07C 6736, C07C 6737, C07C 6916
Patent
active
043190383
ABSTRACT:
The invention relates to an improved process for making 1,1-diacetoxyethane by reacting methyl acetate and/or dimethylether with carbon monoxide and hydrogen under practically anhydrous conditions, at temperatures of 350.degree. to 575.degree. K., under pressures of 1 to 300 bars, and in the presence of a catalyst system containing noble metals belonging to group VIII of the periodic system of the elements, or compounds thereof, and iodine and/or its compounds. The improved process is effected in the presence of a catalyst system containing, as additional ingredients, an aliphatic carboxylic acid having 1 to 8 carbon atoms, a heterocyclic aromatic compound, in which at least one hetero atom is a quaternary nitrogen atom, and a manganese or rhenium compound.
Erpenbach Heinz
Gehrmann Klaus
Kohl George
Kubbeler Hans-Klaus
Garner Vivian
Hoechst Aktiengesellschaft
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