Production method of β-amino acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Reexamination Certificate

active

10765832

ABSTRACT:
A production method of an optically active β-amino acid represented by the formula (I)wherein each symbol is as defined in the specification, which includes reacting a compound represented by the formula (II) with a lithium amide represented by the formula (III) in the presence of a compound represented by the formula (IV).

REFERENCES:
patent: 5679285 (1997-10-01), Bartmann et al.
Hirohisa Doi, Takeo Sakai, Mayu Iguchi, Ken-ichi Yamada, and Kiyoshi Tomioka J.Am.Chem.Soc. 2003, 125,2886-2887.
Derek C. Cole Tetrahedron vol. 50, No. 32, pp. 9517-9582, 1994.
D. Cole, “Recent Stereoselective Synthetic Approaches to Beta-Amino Acids”, Tetrahedron, vol. 50, No. 32, pp. 9517-9582, 1994.
G. Cardillo, et al., “Asymmetric Synthesis of Beta-Amino Acids and Alpha-Substituted Beta-Amino Acids”, Chemical Socited Reviews, 1996, pp. 117-128.
M.P. Sibi, et al., “Chiral Lewis Acid Catalysis in Conjugate Additions of Oxygen-Benzylhydroxylamine to Unsaturated Amides. Enantioselective Synthesis of Beta-Amino Acid Precursors”, J. Am. Chem. Soc., 1998, 120, pp. 6615-6616.
W. Zhuang, et al., “Catalytic Enantioselective Addition of Aromatic Amines to Enones: Synthesis of Optically Active Beta-Amino Acid Derivatives”, Chem. Commun., 2001, pp. 1240-1241.
J. Myers, et al., “Asymmetric Synthesis of Beta-Amino Acid Derivatives Via Catalytic Conjugate Addition of Hydrazoic Acid to Unsaturated Imides”, J. Am. Chem. Soc., 1999, 121, pp. 8959-8960.
G. Sundararajan, et al., “A New Polymer Anchored Chiral Catalyst for Asymmetric Michael Addition Reactions”, Organic Letters, 2001, vol. 3, No. 3, pp. 389-392.
“External Chiral Ligand-Controlled Asymmetric Conjugate Addition of Lithium Amides to Alpha, Beta-Unsaturated Esters” (Report No. 29[P1]l-069), poster Mar. 27, 2003 (see Declaration Under 37 C.F.R. §1.132).
“External Chiral Ligand-Controlled Asymmetric Conjugate Addition of Lithium Amides to Alpha, Beta-Unsaturated Esters” (Report No. 29[P1]l-069), abstract, Mar. 5, 2003 (see Declaration Under 37 C.F.R. §1.132).
“External Chiral Ligand-Controlled Asymmetric Conjugate Addition of Lithium Amides to Alpha, Beta-Unsaturated Esters” (Report No. 29[P1]l-069), internet accessible Feb. 1, 2003 (see Declaration Under 37 C.F.R. §1.132).
H. Doi, et al., “Chiral Ligand-Controlled Asymmetric Conjugate Addition of Lithium Amides to Enoates”, J. Am. Chem. Soc., 125 (10), pp. 2886-2887, 2003, Web Release Date: Feb. 12, 2003 (see Declaration Under 37 C.F.R. §1.132).
H. Doi, et al., “Chiral Ligand-Controlled Asymmetric Conjugate Addition of Lithium Amides to Enoates”, J. Am. Chem. Soc., 125 (10), pp. 2886-2887, Mar. 12, 2003 (see Declaration Under 37 C.F.R. §1.132).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Production method of β-amino acid does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Production method of β-amino acid, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Production method of β-amino acid will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3803706

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.