Production method of high strength polycrystalline ceramic...

Coating processes – With post-treatment of coating or coating material – Heating or drying

Reexamination Certificate

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C427S222000

Reexamination Certificate

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10774319

ABSTRACT:
A method for making hollow spheres of alumina or aluminate comprises: coating polymeric beads with an aqueous solution of an alumoxane, drying the beads so as to form an alumoxane coating on the beads; heating the beads to a first temperature that is sufficient to convert the alumoxane coating to an amorphous alumina or aluminate coating and is not sufficient to decompose the polymeric beads; dissolving the polymeric bead in a solvent; removing the dissolved polymer from the amorphous alumina or aluminate coating; and heating the amorphous alumina or aluminate coating to a second temperature that is sufficient to form a hollow ceramic sphere of desired porosity and strength. The hollow spheres can be used as proppants or can be incorporated in porous membranes.

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patent: 6004525 (1999-12-01), Tani et al.
patent: 6136891 (2000-10-01), Chopin et al.
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American Chemical Society, Joint Southeast-Southwest Regional Meeting “New Chemistry for the New Century”, Dec. 6-8, 2000, pp. 1-4.
DeFriend, Kimberly A., et al; A Simple approach to Hierarchical Ceramic Ultrafiltration Membranes; Journal of Membrane Science; 2003; (pp. 29-38).
DeFriend, Kimberly A., et al; Surface Repair of Porous and Damaged Alumina Bodies Using Carboxylate-Alumoxane Nanoparticles; Journal of Materials Science 37; 2002; (pp. 2909-2916.
Callender, Rhonda L., et al.; Aqueous Synthesis of Water-Soluble Alumoxanes: Environmentally Benign Precursors to Alumina and Aluminum-Based Ceramics 1997 American Chemical Society; (pp. 2418-2433.

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