Production method of 2-(p-alkylphenyl)pyridine compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D213127

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06096894&

ABSTRACT:
A method of producing a 2-(p-alkylphenyl)pyridine compound economically, easily and industrially, which comprises adding manganese dioxide and trimethylchlorosilane, or adding manganese chloride to an organic ether solvent, and reacting p-alkylphenylmagnesium halide and 2-halopyridine in the obtained organic ether solvent.

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Gosmini et al., "Electrochemical Cross-Coupling Between 2-Halopyridines and Aryl or Heteroaryl Halides Catalysed by Nickel-2,2'-Bipyridine Complexes," Tetrahedron, 54, 1289-1298 (1998).
Hitchcock et al., "Selectivity in Palladium (0)-Catalyzed Cross-Coupling Reactions: Application to a Tandem Stille Reaction," Tetrahedron Letters, 36 (50),9085-9088(1995).
Negishi et al., "A Regiospecific Synthesis of Carbosubstituted Heteroaromatic Derivatives Via Pd-Catalyzed Cross Coupling," Heterocycles, 117-122 (1982).

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