Product intended to be used as a photocatalyst, method for the p

Chemistry: electrical current producing apparatus – product – and – Deferred action type – Responsive to light

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204 72, 204 75, 204 77, 204114, 204128, 204129, 204242, 204257, 204278, 204DIG3, 427 74, H01M 636, C25B 100, C25B 102

Patent

active

044277490

ABSTRACT:
The product is in the form of discrete particles or in the form of a layer comprising an electrode. It consists of a semi-conductor material subject to photo-corrosion, for example, cadmium sulphide. In order to prevent such photo-corrosion, the surface of the semi-conductor material, which is intended to be illuminated, is covered with a transparent layer of RuO.sub.2, IrO.sub.2 or a mixture of RuO.sub.2 and IrO.sub.2.
The product may be used for the conversion of solar energy into electric energy or into a fuel such as hydrogen.

REFERENCES:
patent: 4094751 (1978-06-01), Nozik
patent: 4128704 (1978-12-01), McKinzie et al.
patent: 4182796 (1980-01-01), Heller
patent: 4219392 (1980-08-01), Halmann
patent: 4236984 (1980-12-01), Grantham
Chem. Abstr., vol. 94, 93504w (1981).
S. Gourgaud et al., "Semiconductor/Electrolyte Photoelectric Energy Conversion: The Use of a Molybdenum Oxide Coating to Avoid Corrosion", J. Electrochem. Soc., vol. 124, pp. 102-107 (1977).
T. Kawai et al., "Conversion of Carbohydrate into Hydrogen by a Photocatalytic Process", Nature, vol. 286, pp. 474-476 (Jul. 1980).
M. Gratzel, "Photochemical Methods for the Conversion of Light into Chemical Energy", Ber. Bunsenges Phys. Chem., vol. 84, pp. 981-991 (1980).

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