Compositions: coating or plastic – Materials or ingredients – Pigment – filler – or aggregate compositions – e.g. – stone,...
Reexamination Certificate
2002-03-18
2003-07-22
Marcantoni, Paul (Department: 1755)
Compositions: coating or plastic
Materials or ingredients
Pigment, filler, or aggregate compositions, e.g., stone,...
C106S418000
Reexamination Certificate
active
06596072
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention relates to a product and method for dyeing concrete.
For the purposes of this invention, concrete is a cement-containing material for making concrete blocks and concrete slabs, concrete roofing tiles, composite blocks, as well as fibrated cement mortar and/or cement mortar.
Concrete is a proven material of construction and as exposed concrete serves also for aesthetic purposes. Exposed concrete made from a dyed concrete mix will keep its color for many years without need for maintenance.
Concrete is dyed with inorganic pigments, and, more recently, also with organic pigments. Pigments which are suitable for concrete and have proved satisfactory for a prolonged time are manganese oxide, iron oxides and titanium dioxide.
One of the problems of utilizing pigments in the production of dyed concrete is the formation of dust. Dust is raised from the pigment powder and its use results in a soiling of human beings, machines and the surrounding premises. One of the solutions to the dust problem is to form the pigments into granules through the use of a binder. The granular pigment is virtually dust-free, yet will easily flow for mixing with cement to form concrete.
In U.S. Pat. No. 4,946,505 a method is disclosed for forming pigment granules composed of a pigment and a water soluble, organic binder such as lignin sulfonate. The granules disclosed in this patent are formed by a spray drying process. In use, the granules are mixed with cement and water to form a dyed concrete.
Another form of pigment granules used for dyeing concrete is disclosed in U.S. Pat. No. 5,484,481. This patent discloses pigment granules formed from pigments and binders. The binders can be aqueous solutions of at least one inorganic salt taken from the group consisting of phosphate silicates, aluminates and borates. The inorganic salts are all disclosed as being in solution and, accordingly, are water-soluble.
U.S. Pat. No. 5,215,583 also discloses pigment granules for dyeing concrete. The granules of this patent are formed from a pigment and a binder formed from a soluble inorganic salt, such as chlorides, sulfates and phosphates.
U.S. Pat. No. 5,718,755 also discloses pigment granules for dyeing concrete. The granules consist of a pigment and a binder which is a soluble phosphate, silicate or sulphate.
In all of the patents discussed above, where granules are used to solve the dust problems, the binders are water-soluble. U.S. Pat. No. 4,946,505 points out that the soluble binders disclosed therein are dispersing agents, in that they promote the dispersal of the pigment within the concrete.
The granule of this invention enjoys all of the advantages of use of the granules disclosed in the patents discussed above. However, rather than utilizing a soluble binder, the granule of this invention utilizes an insoluble, pozzolanic clay agglomerator. The clay is pozzolanic aluminum silicate.
Although mixtures containing a pozzolan, a pigment and a dispersing agent have been shown to be useful in dyeing concrete, in U.S. Pat. No. 3,068,109, the composition used to dye concrete disclosed in the patent is a powdered mixture. The three components of the powder must be inter-ground before they are added to the concrete mixture, and thus being in a powder form, they will suffer all of the problems of the prior art powdered pigments. These problems were overcome by utilizing the pigment granules disclosed in the patents discussed above.
The pigment granules of this invention operate through a different mechanism from the granules made using a soluble binder of the above patents. Forming granules with a soluble organic binder, such as that disclosed in U.S. Pat. No. 4,946,505, presents potential production problems. The granules of that patent are produced by a spray drying method, during which they are subjected to high temperature air flow for efficiently drying the excess water they contain. Organic substances will burn or char when exposed to temperatures over 400° F. When such exposure occurs, the binder will not be readily soluble in water. Solubility is a condition needed to break the granule bond and free the pigment particles in the concrete to achieve a fast mixing process.
Spray dryers are known to use drying air temperatures well beyond the safe level for organic materials. When using lignin sulfonate for a binder, which is a preferred binder in U.S. Pat. No. 4,946,505, the operating temperature and exposure duration have to be carefully controlled during the spray drying process to prevent burning the lignin sulfonate. However, the temperature must be high enough to dry the pigment granule in a relatively short time. This is a critical condition that presents a limited window for processing. Organic binders, such as lignin sulfonate, are also known to negatively affect the hydration of the cement in the concrete and promote undesirable efflorescence, and it is important not to exceed a certain critical level.
The process limitations are eliminated when utilizing the aluminum silicate complex of this invention. Aluminum silicate clays are naturally formed, and maybe refined by further processing. The clay has to be hydrophilic or hydraulic to allow its incorporation in the water suspension used in either of the granulating processes disclosed hereinafter. Examples of pozzolanic clays usable in this invention are bentonite and metakaolin, which is subsequently calcined.
Unlike organic binders, clays do not effect negatively the hydration of the cement. Hydraulic pozzolan clays enhance the concrete properties. Pozzolans, which are silicate rich, lime poor, react with the calcium hydroxide, produced by cement hydration, to produce cementitious sites locked to the cement structure.
Clays can withstand very high temperatures and are not affected by the processing temperatures used in the production of granulated pigments. The possible burning and charring of the binder is thus avoided. Because clays are not film forming, water can easily penetrate the crystalline structure of the granule, and quickly break down the bond between pigment and clay.
SUMMARY OF THE INVENTION
Pigment-containing granules comprising at least one pigment selected from the group consisting of manganese oxide and iron oxide and an agglomerator, said agglomerator comprising a hydrophilic clay.
DETAILED DESCRIPTION OF THE INVENTION
The clay used as an agglomerator for the pigment is inorganic and insoluble in water. A preferred clay is calcined pozzolan clay, which is hydrophilic (hydraulic). That is, it will readily absorb water. A preferred clay is hydrophilic pozzolanic aluminum silicate.
The pozzolanic aluminum silicate is naturally occurring. It is further processed by calcining, that is, heating to temperatures in excess of 1000° C. The high temperature will burst the clay particle, increasing its surface area and turning it into a highly absorbent material. The pozzolanic attribute of the clay causes it to react with the calcium oxide present in the cement, which enables it to anchor itself to the hydrating cement.
The granules are used in the same manner as the pigment-containing granules of the prior art. Thus, they are mixed with water and cement to form colored concrete.
The granules formed from the pozzolanic clay have a number of advantages over the prior art granules containing soluble binders. The clay forms additional cementitious sites locking the color into the concrete. This results in improvement in the physical performance of the concrete. Unlike the organic binders, pozzolan clays do not have any adverse effect on the concrete.
The prior art soluble organic binders are film-forming around the pigment particles. When used to color cement, the process is time-dependent on the dissolution of the film binder. Contrasted with this, water readily penetrates the clay granule between the pigment particles and re-wets the clay, freeing the pigment particles to allow them to mix promptly with the cement in the formation of the concrete.
Although the pozzolanic aluminum silicate clay can broadly
Dunnous Jack
Yocum William J.
Caesar Rivise Bernstein Cohen & Pokotilow Ltd.
Hamburger Color Company
Marcantoni Paul
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