Producing sulphur-nitrogen groups

Chemistry of inorganic compounds – Nitrogen or compound thereof – Binary compound

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423351, 423467, C01B 1700, C01B 1745

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active

042684919

ABSTRACT:
Compounds containing sulphur-nitrogen groups, such as S.sub.4 N.sub.4, S.sub.5 N.sub.5.sup.+ salts and poly(sulphur nitride), are made by reducing S.sub.4 N.sub.3 Cl or related compounds with anions (e.g. iodide) or metals (e.g. silver). Poly(sulphur nitride) may be made by passing S.sub.4 N.sub.3 Cl vapor or S.sub.5 N.sub.5 FeCl.sub.4 vapor through sulphidized silver wool and condensing the vapor.

REFERENCES:
patent: 3384461 (1968-05-01), Beck
Muthmann W. et al., "Z. Anorg., und Allgem. Chem." 1896, 13, pp. 200-208.
"Chem. Abst.", vol. 75, 1971--104648g.
"Chem Abst.", vol. 75, 1971--136665b and 136669f.
"Chem. Abst.", vol. 81, 1974--72075y.
Mikulski, C. M. et al., J.A.C.S., Oct. 29, 1975-pp. 6358--6363.

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