Producing epoxide from olefin using metal nitro complexes

Details Producing epoxide from olefin using metal nitro complexes Producing epoxide from olefin using metal nitro complexes

1981-12-21

1982-10-26

Milestone, Norma S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30103

Patent

active

043563112

ABSTRACT:
An olefinically unsaturated substrate is reacted with a transition metal nitro complex, having the transition metal bonded to the nitrogen of the nitro radical, in the presence of a thallium(III) compound as cocatalyst to cause the production of oxirane products, rather than aldehydes or ketones. The process is applicable to the production of ethylene oxide, propylene oxide, epichlorohydrin, epoxidized fatty acids and oxiranes from various other internal and terminal olefins.

REFERENCES:
patent: 3436409 (1969-04-01), Hill
patent: 3641067 (1972-02-01), Kruse
patent: 3935272 (1976-01-01), Chapurlat
patent: 4021453 (1977-05-01), Brill
patent: 4146545 (1979-03-01), Leonard
patent: 4290959 (1981-09-01), Barker

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