Producing alkoxysilanes and alkoxy-oximinosilanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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556471, C07F 710, C07F 718

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active

043806600

ABSTRACT:
A silicon halide such as methyl trichlorosilane is reacted with an alcohol such as isopropanol and an oxime such as methyl ethyl ketone oxime. Byproduct oxime hydrohalide is formed in all cases. With higher amounts of alcohol, alkoxysilane (e.g. methyl triisopropoxysilane) is the sole or major product. With lower amounts of alcohol, alkoxy-oxminosilanes (e.g. methyl diisopropoxy(methyl ethyl ketoximo)silane and methyl isopropoxy bis(methyl ethyl ketoximo)silane) are the major products.

REFERENCES:
patent: 3277136 (1966-10-01), Thiesse
patent: 3448136 (1969-06-01), Pande et al.
patent: 3546267 (1970-12-01), Ismail
patent: 4126630 (1978-11-01), Muller et al.
Chemical Abstracts, vol. 83:179292k.
Chemical Abstracts, vol. 75;89238c.
Chemical Abstracts, vol. 80:4671u.

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