Processing nonferrous metal hydroxide sludge wastes

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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423 40, 423 53, 423 54, 423127, 423132, 423139, 423150, C01G 310, C01G 3714, C01G 906, C01G 5310

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active

041512570

ABSTRACT:
A method for recovering nonferrous metal values from hydroxide sludge wastes containing same by first chlorinating the aqueous waste to oxidize the chromium therein, separating the insoluble components therefrom and treating the resulting Cr(VI) solution in a fixed bed anion exchanger to separate the Cr(VI) from the solution, separating the copper from the aqueous solution by liquid-liquid extraction, separating the zinc from the copper-free solution by liquid-liquid extraction, precipitating and separating the aluminum in the form of hydroxide from the zinc-free solution and then separating the nickel from the aluminum-free solution by liquid-liquid extraction, and recovering the nonferrous metals from the respective solutions and precipitates by conventional procedures.

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patent: 3856916 (1974-12-01), Lefrancois et al.
patent: 3966569 (1976-06-01), Reinhardt et al.
patent: 4009101 (1977-02-01), Hayashi
patent: 4029733 (1977-06-01), Faugeras et al.
Reinhardt, H., "Solvent Extraction for Recovery of Metal Waste", Chemistry and Industry, Mar. 1, 1975, pp. 210-213.

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