Processes of making γ,δ-unsaturated carboxylic...

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

Reexamination Certificate

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C556S431000, C556S432000, C556S440000, C556S442000, C556S465000, C556S466000, C556S479000, C556S482000, C562S598000

Reexamination Certificate

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10947129

ABSTRACT:
A γ,δ-unsaturated carboxylic acid silyl ester is prepared by reacting an α,β-unsaturated carboxylic acid ester with a hydrosilane or hydrosiloxane in the presence of tris(pentafluorophenyl)borane. γ,δ-Unsaturated carboxylic acid derivatives are readily prepared through fewer steps and in high yields.

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Urabe et al., Journal of Organic Chemistry, vol. 49, No. 6, pp. 1140-1141 (1984).
Qingdao Haiyang Daxue Xuedao, 1999, vol. 29, pp. 319 to 320.
Trost and Fleming Ed., Comprehensive Organic Synthesis, First Edition, Pergamon Press, 1991 pp. 827 to 873.

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