Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives
Reexamination Certificate
2005-03-25
2009-10-06
Jiang, Shaojia Anna (Department: 1623)
Organic compounds -- part of the class 532-570 series
Organic compounds
Carbohydrates or derivatives
C568S864000
Reexamination Certificate
active
07598374
ABSTRACT:
Methods of producing xylitol comprising the oxidative decarboxylation of a reactant substrate are provided herein. The oxidative decarboxylation is performed in one of two ways. In the first, the oxidative decarboxylation is performed by an electrochemical process, preferably an anodic odixative decarboxylation of a reactant substrate. In the second, the oxidative decarboxylation of the reactant substrate is carried out by a series of oxidation-reduction chemical reactions.
REFERENCES:
patent: 2852567 (1958-09-01), Barnard et al.
patent: 2989569 (1961-06-01), Apel
patent: 3558725 (1971-01-01), Kohno et al.
patent: 3619369 (1971-11-01), Onishi et al.
patent: 3627636 (1971-12-01), Jaffe et al.
patent: 3784408 (1974-01-01), Jaffe et al.
patent: 3980719 (1976-09-01), Buckl et al.
patent: 3992268 (1976-11-01), Antos
patent: 4008285 (1977-02-01), Melaja et al.
patent: 4066711 (1978-01-01), Melaja et al.
patent: 4075406 (1978-02-01), Melaja et al.
patent: 4125559 (1978-11-01), Scholz et al.
patent: 4429140 (1984-01-01), Murai et al.
patent: 4617090 (1986-10-01), Chum et al.
patent: 4742814 (1988-05-01), Sinner et al.
patent: 4950366 (1990-08-01), Jiricny et al.
patent: 5045340 (1991-09-01), Kohler et al.
patent: 5081026 (1992-01-01), Heikkila et al.
patent: 5096820 (1992-03-01), Leleu et al.
patent: 5162517 (1992-11-01), Darsow et al.
patent: 5536526 (1996-07-01), Virtanen et al.
patent: 5563303 (1996-10-01), Vuorinen et al.
patent: 5616361 (1997-04-01), Virtanen et al.
patent: 5631150 (1997-05-01), Harkki et al.
patent: 5686277 (1997-11-01), Kim et al.
patent: 5714602 (1998-02-01), Beck et al.
patent: 5831078 (1998-11-01), Elseviers et al.
patent: 5998181 (1999-12-01), Kim et al.
patent: 5998607 (1999-12-01), Heikkila et al.
patent: 5998608 (1999-12-01), Tamion
patent: 6221634 (2001-04-01), Takeuchi et al.
patent: 6245940 (2001-06-01), Tamion
patent: 6271007 (2001-08-01), Apajalahti et al.
patent: 6303353 (2001-10-01), Sugiyama et al.
patent: 6335177 (2002-01-01), Mihara et al.
patent: 6340582 (2002-01-01), Suzuki et al.
patent: 6458570 (2002-10-01), Elseviers et al.
patent: 6476217 (2002-11-01), Tamion
patent: 6538133 (2003-03-01), Aoki et al.
patent: 6723540 (2004-04-01), Harkki et al.
patent: 6764706 (2004-07-01), Heikkila et al.
patent: 6846657 (2005-01-01), Heikkila et al.
patent: 2002/0076772 (2002-06-01), Elseviers et al.
patent: 2002/0164731 (2002-11-01), Eroma et al.
patent: 2003/0068791 (2003-04-01), Miasnikov et al.
patent: 2003/0097029 (2003-05-01), Heikkila et al.
patent: 2003/0125588 (2003-07-01), Heikkila et al.
patent: 2003/0235881 (2003-12-01), Heikkila et al.
patent: 2004/0002054 (2004-01-01), Horvitz et al.
patent: 2004/0014185 (2004-01-01), Ojamo et al.
patent: 2004/0132074 (2004-07-01), Verho et al.
patent: 2004/0142456 (2004-07-01), Jeffries et al.
patent: 2004/0191881 (2004-09-01), Raj et al.
patent: 1381585 (2002-11-01), None
patent: 274 796 (1990-02-01), None
patent: 102 58 089 (2004-06-01), None
patent: 0 421 882 (1991-04-01), None
patent: 0 421 882 (1991-04-01), None
patent: 57-128697 (1982-08-01), None
patent: 58-039695 (1983-03-01), None
patent: 2004-24140 (2004-01-01), None
patent: WO 02/06504 (2002-01-01), None
patent: WO 02/088154 (2002-11-01), None
patent: WO 02/088155 (2002-11-01), None
patent: WO 03/097848 (2003-11-01), None
patent: WO 2004/048559 (2004-06-01), None
patent: WO 2004/052813 (2004-06-01), None
patent: WO 2004/085627 (2004-10-01), None
patent: WO 2004/108739 (2004-12-01), None
patent: WO 2005/010171 (2005-02-01), None
U.S. Appl. No. 10/341,220, filed Jan. 2003, Ojamo.
Bragd, P.L. et al.; Selective Oxidation of Carbohydrates by 4-AcNH-TEMPO/peracid Systems; Carbohydrate Polymers 49; pp. 397-406; 2002.
De Faveri, D., et al., Optimization of xylitol recovery by crystallization from synthetic solutions using response surface methodology. Journal of Food Enginering, vol. 61, 407-412 (2004).
Ji{hacek over (r)}i{hacek over (c)}n{dot over (y)}, V. et al.; Preparation of D-arabinose in a Laboratory Fluidized Bed Electrode Cell; Collect. Czech. Chem. Commun. vol. 60; pp. 863-874; 1995.
Ji{hacek over (r)}i{hacek over (c)}n{dot over (y)}, V. et al.; Production of D-arabinose in a Pilot Plant Fluidized Bed Electrochemical Reactor; Journal of Applied Electrochemistry 24; pp. 930-935; 1994.
Kochetkov, N.K., et al., Selective cleavage of glycuronosidic linkages. Carbohydrate Research, vol. 14, 277-285 (1970).
Matsuoka, K., et al., Anoidic oxidation of polyhydric alcohols on a Pt electrode in alkaline solution. Fuel Cells (Weinheim, Germany) 2, 35-39 (2002).
Pergola, F., et al., Direct electro-oxidation of D-gluconic acid to D-arabinose. Electrochimica Acta 39, 1415-1417 (1994).
Pezzatini, G., et al., Electro-oxidative decarboxylation of D-gluconic acid to D-arabinose on graphite electrodes. Electroanlaysis, vol. 4, 129-132 (1992).
Schuurman, Y., et al., Selective oxidation of methyl α-D-glucoside on carbon supported platinum. In “New Developments in Selective Oxidation by Heterogeneous Catalysis”, Ruiz, P.; and Delmon, B., eds., vol. 72 of “Studies in Surface Science and Catalysis”, 1992, pp. 43-55.
Schuurman, Y., et al., Selective oxidation of methyl α-D-glucoside on carbon supported platinum. II. Assessment of the Arrhenius and Langmuir parameters. Applied Catalysis A: General, vol. 89, 31-46 (1992).
Schuurman, Y., et al., Selective oxidation of methyl α-D-glucoside on carbon supported platinum. III. Catalyst deactivation. Applied Catalysis A: General, vol. 89, 47-68 (1992).
Taylor, R.L. Sorbitol from glucose by electrolytic reduction. Chemical and Metallurgical Engineering, vol. 44, 588-591 (1937).
Vallieres, C., and Matlosz, M., A multisectioned porous electrode for synthesis of D-arabinose. Journal of the Electrochemical Society 146, 2933-2939 (1999).
International Search Report for International Application No. PCT/US05/10377.
Emil Fischer and Otto Ruff, “On the conversion of gulonic acid to xylose and galactose,”Berichte der Deutschen Chemischen Gesellschaft, 33:2142-2147 (1900).
Carl Neuberg, “Electrolysis in the Sugar Series,”Biochemische Zeitschrift, 7:537-538 (1908).
Joseph Kiss, Richard D'Souza and Paul Taschner, “Preparative production of 5-deoxy-L-arabinose, xylitol and D-ribose from ‘giacetone glucose’,”Helvetica Chimica Acta58:311-317 (1975).
BeMiller James N.
Stapley Jonathan A.
Brinks Hofer Gilson & Lione
Jiang Shaojia Anna
Purdue Research Foundation
White Everett
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