Processes for the production of sulphur-containing esters of pho

Chemistry of carbon compounds – Dipeptides – e.g. – aspartame – anserine – carnosine – etc.

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260967, C07F 9201

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active

041894537

ABSTRACT:
Trithio- and tetrathiophosphates with mercaptocarboxylic acid derivatives are preeminently suitable as extreme pressure additives for lubricants. They reduce signs of wear and have no or only an insignificant corrosive action on the parts to be protected. They are obtained in high yields, shorter reaction times and relatively free from by-products via the trithiophosphites by reaction of phosphorus trihalides with mercaptans in the presence of a catalyst and subsequent oxidation with sulphur or an oxygen donor.

REFERENCES:
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patent: 2943107 (1960-06-01), Rattenbury et al.
patent: 3374291 (1966-03-01), Myers
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patent: 3751529 (1973-08-01), Baker et al.
patent: 3772414 (1973-11-01), Baker et al.
patent: 3773716 (1973-11-01), Rattenbury
patent: 3773866 (1973-11-01), Baker et al.
patent: 3922325 (1975-11-01), Anderson
patent: 3965220 (1976-06-01), Schumacher
patent: 3968188 (1976-07-01), Birum et al.
Houben-Weyl, vol. 12/2, pp. 93-95, and 742-748.
Schmiermittel Taschenbuch, Huthig Verlag, Heidelberg, 1974, vol. 15, pp. 229-232.

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