Processes for the preparation of fluorinated olefins and hydrofl

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570134, 570135, 570157, 570158, 570167, 570172, C07C 1720, C07C 1725, C07C 17266, C07C 17275

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active

054462177

ABSTRACT:
The invention relates to a cost effective and convenient process for the manufacture of fluorinated olefins of the formula RCF.sub.2 CH=CH.sub.2 where R is C.sub.x Cl.sub.y F.sub.z and y+z=2x+1. The invention is also directed to a practical process for converting these olefins to hydrofluorocarbons via the catalyzed fluorination with hydrogen fluoride. Hydrofluorocarbons produced via this process have application as solvents among other uses.

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Brace, et al., "Effect of a Perfluoroalkyl Group on the Elimination and Substitution Reactions of Two Homologous Series of Perfluoroalkyl-Substituted Iodoalkanes", 49 J. Org. Chem., 2361 (1984).
Henne et al., "Influence of a CF.sub.3 Group On An Adjacent Double Bond, 72 J. Am. Chem. Soc.", 3369 (1950).
Chem. Abstr. 1992, 117: 69439b.

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