Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1997-04-15
1998-10-13
Geist, Gary
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568451, C07C 4550
Patent
active
058213899
ABSTRACT:
This invention relates in part to processes for producing one or more substituted or unsubstituted hydroxyaldehydes, e.g., 6-hydroxyhexanals, which comprise subjecting one or more substituted or unsubstituted alkadienes, e.g., butadiene, to reductive hydroformylation in the presence of a reductive hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, and hydroformylation in the presence of a hydroformylation catalyst, e.g., a metal-organophosphorus ligand complex catalyst, to produce one or more substituted or unsubstituted hydroxyaldehydes. The substituted and unsubstituted hydroxyaldehydes produced by the processes of this invention can undergo further reaction(s) to afford desired derivatives thereof, e.g., epsilon caprolactone. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted hydroxyaldehydes as principal product(s) of reaction.
REFERENCES:
patent: 3239566 (1966-03-01), Slaugh et al.
patent: 3660493 (1972-05-01), Johnson et al.
patent: 3947503 (1976-03-01), Kummer
patent: 4185038 (1980-01-01), Carlock
patent: 4189448 (1980-02-01), Carlock
patent: 4198352 (1980-04-01), Kim et al.
patent: 4200591 (1980-04-01), Hignett et al.
patent: 4200592 (1980-04-01), Hignett et al.
patent: 4214109 (1980-07-01), Carlock
patent: 4224255 (1980-09-01), Smith
patent: 4263449 (1981-04-01), Saito et al.
patent: 4376212 (1983-03-01), Ohyama et al.
patent: 4409418 (1983-10-01), Johnson et al.
patent: 4443638 (1984-04-01), Yates
patent: 4447661 (1984-05-01), Hoshiyama et al.
patent: 4451679 (1984-05-01), Knifton et al.
patent: 4469895 (1984-09-01), Knifton et al.
patent: 4482749 (1984-11-01), Dennis et al.
patent: 4528404 (1985-07-01), Oswald et al.
patent: 4567306 (1996-01-01), Dennis et al.
patent: 4625068 (1986-11-01), Young
patent: 4647707 (1987-03-01), van Vliet
patent: 4658068 (1987-04-01), Henin
patent: 4769498 (1986-09-01), Billig et al.
patent: 5177228 (1930-01-01), Sato et al.
patent: 5306848 (1994-04-01), Vargas
patent: 5312996 (1994-05-01), Packett
patent: 5434312 (1995-07-01), Fell et al.
patent: 5504261 (1996-04-01), Mullin et al.
patent: 5583250 (1996-12-01), Bahrmann et al.
J.M. Anderson, et al. Improved regioselectivity in the hydroformylation reaction catalysed by zeolite-encapsulated rhodium(I) species, Chem. Commun. 1996, pp. 1543-1544.
J.K. MacDougall, et al. Metal Hydroxycarbene-Like Intermediates in the Hydrocarbonylation of Alekenes to Alcohols Catalysed by Rhodium Complexes, Polyhedron, vol. 12,No. 23, pp. 2877-2881 (1993).
M.C. Simpson, D.J. Cole Hamilton/Coordination Chemistry Reviews 155 (1996) 163-207 pp. 186-207.
Chem Abstracts 1972, 77, 125982t-Catalytic hydroformylation of olefins Lawrenceson, Malcolm John (EP Chemicals Ltd.).
Briggs John Robert
Brigham Elaine Susan
Bryant David Robert
Eisenschmid Thomas Carl
Guram Anil Sakharam
Coon Gerald L.
Geist Gary
Padmanabhan Sreeni
Union Carbide Chemicals & Technology Corporation
LandOfFree
Processes for producing hydroxyaldehydes does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Processes for producing hydroxyaldehydes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Processes for producing hydroxyaldehydes will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-314418