Processes for polyurethane polymerization using polysilyl...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

Reexamination Certificate

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C528S056000, C502S242000

Reexamination Certificate

active

07625992

ABSTRACT:
Processes for polyurethane polymerization are provided. The processes use polysilyl derivatives of germanium and tin as catalysts. Polyurethanes made using the catalysts have increased gel times as compared to polyurethanes made using conventional processes.

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Brook, A.G. et al., “Synthesis of Some Tris(Trimethylsilyl)Germyl Compounds”, J. Organometallic Chemistry, 299 (1986), pp. 9-13.
Mallela, S.P. et al., “Synthesis and Characterization of Hexakis(Trimethylsilyl)Digermane and -Distannane”, Inorg. Chem., 1993, 32, pp. 5623-5625.
Dolbier Jr., W.R. et al., “A New and Practical Synthesis of Octafluoro(2.2)Paracyclophane”, J. Org. Chem., 1997, 62, pp. 7500-7202.

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