Processes for controlling the viscosity of polyalphaolefins

Chemistry of hydrocarbon compounds – Compound or reaction product mixture – Polymer of indefinite molecular weight

Reexamination Certificate

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Details

C585S523000, C526S133000, C526S134000, C526S160000, C526S165000, C526S348200, C526S348300, C526S943000

Reexamination Certificate

active

08067652

ABSTRACT:
The invention relates to a process for forming a polyalphaolefin, the process comprising the step of polymerizing at least one C8-C12monomer, preferably a decene such as 1-decene, in the presence of an aluminoxane, an activator and a metallocene to form the polyalphaolefin, wherein the molar ratio of the aluminoxane to the metallocene is less than 250:1. The invention also relates to a process for forming a polyalphaolefin having a desired kinematic viscosity from at least one monomer in the presence of an aluminoxane, an organoboron compound and a metallocene. The process comprises the steps of, inter alia, providing a correlation between (i) the molar ratio of the aluminoxane to at least one of the organoboron compound and the metallocene, and (ii) the kinematic viscosity of the polyalphaolefin to form polyalphaolefins having predictable viscosities.

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