Liquid purification or separation – Processes – Separating
Reexamination Certificate
2002-03-26
2004-06-29
Popovics, Robert (Department: 1724)
Liquid purification or separation
Processes
Separating
C210S803000, C414S217000, C414S221000
Reexamination Certificate
active
06755980
ABSTRACT:
The present invention is directed to a process to remove solid slag from a mixture of solid slag and water present in a quench zone, which quench zone is part of a process for the preparation of synthesis gas by partial combustion of finely dispersed solid carbon-containing fuel with an oxygen-containing gas. Such a process is described in EP-A-290087. In this process a mixture of water and solid slag is batchwise sluiced out of a pressurized gasification system. Liquid slag is a by-product of the gasification or partial combustion of, for example, coal. Liquid slag is drained through the outlet located at the reactor bottom and passed by gravity through a slag discharge means into a water bath or slag quenching vessel where the mixture of water and solid slag particles are formed. The batchwise sluicing of the mixture from the pressurized gasification system to a lower-pressure discharge zone is performed by means of a lockhopper. During the sluicing cycle the lockhopper is isolated from the gasification system by closing one or more valves in the connecting line between the slag quench vessel and the lockhopper.
A problem of this sluicing procedure is that, when the valve between the lockhopper and the quench vessel is closed, the slag accumulating up-stream this valve has a tendency for bridging at the narrow space just above the said valve. It has appeared very difficult to have the slag to fall into the lockhopper after reconnecting the lockhopper to the gasification system. This problem is solved by the process disclosed in EP-A-290087, wherein a permanent nitrogen-gas bubble or nitrogen-gas cap is maintained in the lockhopper. By ensuring that the pressure of the said nitrogen gas bubble is lower than the pressure in the slag quench vessel an initial downwards flow of water and slag during opening of the valves between the lockhopper and the slag quench vessel is achieved. This method also results in a quick discharge of the slag from the quench vessel into the lockhopper.
Although the above process has proven to work satisfactory in commercial practice it still has some disadvantages. One disadvantage is the need to install additional equipment to supply nitrogen and the associated costs of the nitrogen consumption during every sluicing cycle. A further disadvantage is that together with the discharged mixture an amount of sulphur compounds, of which hydrogen sulphide is the most prominent, and other dissolved components, for example ammonia, chloride and carbon monoxide, are also discharged. Hydrogen sulphide is formed in the reactor from sulphur containing compounds which are present in the hydrocarbon feed. Part of the hydrogen sulphide will dissolve in the water present in the slag quench vessel and will thus be discharged together with the slag in the above described process.
The object of the present invention is a simple process to quickly separate solid slag particles from a quench zone, containing a mixture of said slag particles and water, such that no or very little sulphur containing compounds are being removed with the slag from the quench zone.
This object is achieved by the following process. Process to remove solid slag particles from a mixture of solid slag particles and water present in a quench zone, which quench zone is part of a process for the preparation of synthesis gas by partial combustion of finely dispersed solid carbon-containing fuel with oxygen-containing gas, by
(a) discharging of the mixture from the quench zone to a first vessel,
(b) discharging slag particles from the first vessel to a second vessel by means of gravity, which second vessel is located below and fluidly connected to said first vessel by means of an open connecting conduit and is further provided with closed means to discharge slag from its lower end, and discharging water poor in solid slag from the second vessel via a conduit provided with. pumping means and having an inlet located such that water poor in slag particles are pumped from the second vessel,
(c) fluidly closing the first vessel from the second vessel,
(d) opening of the means to discharge slag from the second vessel to remove slag from the second vessel to a lower pressure zone, and
(e) closing the means to discharge slag from the second vessel and repeating steps (a) to (e).
By performing the process according the invention it is possible to discharge solid slag particles from a vessel containing a mixture of liquid and solid slag particles, wherein the amount of sulphur containing compounds being discharged together with the water is lower than in prior art processes. Less hydrogen sulphide will thus be discharged together with the slag particles. The hydrogen sulphide normally discharged together with the slag will now be discharged with the synthesis product gases. Because the synthesis gases typically contain a certain amount of hydrogen sulphide it will be no problem to remove this additional amount of hydrogen sulphide in the existing downstream hydrogen sulphide removal sections. Further advantages of the present process will become apparent when reading the detailed description of this invention.
The present process is directed to separate slag particles from a process for the preparation of synthesis gas by partial combustion of finely dispersed solid carbon-containing fuel with an oxygen-containing gas. Examples of carbon-containing fuel are coal, peat, wood, coke, for example petroleum coke, soot, carbon containing waste, biomass and mixtures of these. Mixtures of the aforementioned feedstocks and metal containing waste streams can also be used as feed.
The ratio of volume of water poor in slag, which is extracted from the second vessel, relative to the volume of solids passing conduit from the first vessel to the second vessel in the same time period is preferably between 0.7 and 1.5 and more preferably between 0.8 and 1. Most preferably the volume of liquid extracted from the second vessel and supplied to the first vessel is about the same as the volume of solids passing from the first to the second vessel due to gravity. The liquid in the connecting conduit between first and second vessel will then be kept close to stagnant. This situation further reduces any sulphur compounds from entering the second vessel.
Preferably the mass flux of the slag particles in the connecting conduit between the first and second vessel is between 100-150 kg slag particles per square meter of the cross sectional area of the conduit or valve, whatever the smallest, per second (kg/m
2
/s).
Because a first vessel is present between the quench zone and the second vessel or lockhopper a gradient in the concentration of sulphur compounds will be present, wherein the concentration of sulphur compounds in the first vessel will be lower than in the quench zone. This concentration gradient is especially achieved when the height over diameter ratio of the first vessel is greater
5
than three. Preferably the water poor in slag extracted from the second vessel is fed to the lower end of the first vessel to further increase this concentration gradient. This concentration gradient is advantageous because it further reduces the chances of any sulphur compounds entering the second vessel.
The volume of the first vessel is preferably of the same size or larger than the second vessel. The additional volume acts as buffer capacity for problem solving and in addition reduces the chances of any sulphur compounds entering the second vessel. When closing the first vessel from the second vessel in step (c) preferable no or very few slag particles will be present in the connecting conduit, thereby reducing the chance that slag particles obstruct the valve present in said conduit, thereby reducing the change on damaging the valve, and keeping the buffer capacity available to anticipate for problems that may rise. The second vessel is preferably not too small because this will result in a too high sluicing frequency, resulting in a poor capacity of the process. Suitably the volume of the first vessel is between 2 and 3 times the volume
Schilder Johannes Gerardus Maria
Van Den Born Isaac Cornelis
Popovics Robert
Shell Oil Company
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