Process to regulate olefin production by catalyst system inhibit

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585513, 585523, 502167, C07C 224, B01J 3100

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active

056890281

ABSTRACT:
A process is provided to inhibit trimerization catalyst system activity which comprises the sequential steps of contacting a reactor effluent stream with alcohol; removing any desired olefin products; adding an aqueous base to the non-olefin portion; removing a precipitate; separating the aqueous and organic phases; and adding an acid to the aqueous phase.

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Briggs, John R.; Journal Chem. Soc., Chem. Commun. "The Selective Trimerization of Ethylene to Hex-1-ene", (1989), pp. 674-675.

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