Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur
Patent
1981-07-15
1983-07-26
Thomas, Earl C.
Chemistry of inorganic compounds
Sulfur or compound thereof
Elemental sulfur
423237, 423574R, B01D 1704
Patent
active
043953905
ABSTRACT:
A process to produce sulphur from two acid gases both containing hydrogen sulphide and one of which contains ammonia, using a modified Claus technique.
The acid gas containing ammonia is burnt in the presence of air under substoichiometric conditions in a first heat-reaction chamber, while the ammonia-free acid gas is burnt in a second heat-reaction chamber, forming a series with the first chamber, with the right quantity of air to provide a molar ratio of H.sub.2 S to SO.sub.2 of approximately 2/1 at the catalytic reaction stage inlet. The mixed effluents from both heat-reaction chambers may pass through a high-temperature residence chamber before being conveyed to the heat-recovery stage.
Gas effluents from the heat-reaction stage contain H.sub.2 S and SO.sub.2 in the right ratio for the catalytic reaction stage, and no hydrocarbons or harmful quantities of NH.sub.3 and NO.
REFERENCES:
patent: 3957960 (1976-05-01), Palm et al.
patent: 3970743 (1976-07-01), Beavon
patent: 4035158 (1977-07-01), Scott et al.
patent: 4101642 (1978-07-01), Tippmer
Blanc Claude
Desgrandchamps Guy
Kvasnikoff Georges
Societe Nationale Elf Aquitaine
Thomas Earl C.
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