Process to produce disproportionated rosin based emulsifier for

Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – Process of making a soap containing composition by...

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510460, 510486, 510487, 2523671, 530212, 530213, 530225, 530226, 530227, 530230, 530233, C11D 1504, C09F 104

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active

060873183

ABSTRACT:
A process for disproportionating rosins using iodide catalysts. In one embodiment, a tall oil rosin is heated in the presence of a lithium iodide catalyst. In another embodiment, a catalyst system is formed from a mixture of lithium iodide and ferrous iodide. The mixed catalyst system completes disproportionation of tall oil rosin in about three hours. Phosphoric acid may be added to remove iron colored impurities when using the mixed catalyst system. Another aspect of the invention involves preparing a soap from the disproportionated rosin by adding a defoamer and a base, such as potassium hydroxide.

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