Process to prepare diazinon

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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544319, C07F 96512

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055719163

ABSTRACT:
Diazinon is prepared by coverting the starting hydroxypyrimidine to its potassium salt by reacting it with potassium carbonate in an organic solvent after removal of the water by azeotropic distillation, and reacting the resulting non-aqueous salt with diethyl thiophosphoryl chloride and recovering the diazinon formed, wherein the quantity of potassium carbonate used relative to the starting hydroxypyrimidine is less than molar and desirably of a ratio in the range of 0.55 to 0.75.

REFERENCES:
patent: 2754243 (1956-07-01), Gysin et al.
patent: 3951975 (1976-04-01), Hofer et al.
patent: 4066642 (1978-01-01), Sury et al.
patent: 4326059 (1982-04-01), Gargano et al.
patent: 5034529 (1991-07-01), Freeman
patent: 5231180 (1993-07-01), Gurfinkel et al.

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