Process to make 2,3-dihalopropanols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3134

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057446555

ABSTRACT:
A 2,3-dihalopropanol is made by reacting 2,3-dihalopropanal with a hydrogenating agent in the presence of a transition metal-containing catalyst, under conditions such that 2,3-dihalopropanol is formed. The reaction is particularly useful as Step (3) in a process to make epihalohydrin by:

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Sanchez-Delgado et al., "Homogeneous Hydrogenation of Aldehydes to Alcohols with Ruthenium Catalysts", Journal of Organometallic Chemistry, vol. 209, No. 1, pp. 77-83 (Apr. 7, 1981).

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