Process of synthesis of organic substances by an indirect electr

Details Process of synthesis of organic substances by an indirect electr Process of synthesis of organic substances by an indirect electr

1989-01-06

1992-01-28

Niebling, John F.

Chemistry: electrical and wave energy

Processes and products

204 78, C25B 302

Patent

active

050841475

ABSTRACT:
A process of oxidation or reduction of organic substrates by an indirect electrochemical route is described. During oxidation, the electrochemical stage produces a metallic oxide having higher valence such as RuO.sub.2, NiOOH, which is applied to an inert conductor support. The supported metallic oxide of higher valence is separated from the aqueous electrolyte and is then placed in contact with the pure organic material to be reacted on. The metallic oxide in this manner is reduced to a lower valence and is subjected to a new electrochemical oxidation after the residues of the organic material are removed. The process consists of a cyclic repetition of these stages. The process of reduction of organic substrates is analogous and is carried out by means of the hydrogen of hydrides formed through a cathodic charge by electrolysis of an aqueous solution.

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