Process of refining sodium hexafluorosilicate

Chemistry of inorganic compounds – Silicon or compound thereof – Halogen containing

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423155, 423184, 423202, C01B 3310

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041615115

ABSTRACT:
Crude sodium hexafluorosilicate containing gypsum and various metal phosphates is refined into highly pure and sufficiently large crystals. First, the crude fluorosilicate is treated with a sodium chloride solution to dissolve gypsum. Then the solid phase is reconstituted into an aqueous slurry in which the concentration of Na is limited. This slurry is acidified and maintained at temperatures not lower than 80.degree. C. with continued stirring to cause recrystallization of sodium hexafluorosilicate.

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patent: 3607016 (1971-09-01), Barilli
patent: 3795728 (1974-03-01), Scheel
patent: 3915659 (1975-10-01), Kadotani et al.
patent: 4060586 (1977-11-01), Sardisco et al.

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